A lot of sportsbooks in Mexico City will have the NFL games on - NFL is popular in Mexico, look how many people attended the preseason game a year or two ago, in Guadalajara.
Or, Mexico City has a lot of legal bookmaking establishments, where the games will be shown (and bets accepted on). Ask at the desk of your hotel, one may be within walking distance. (Or better, take a cab. Mexico City can be dangerous for unwary tourists.)
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